1,328 research outputs found
Tuning surface metallicity and ferromagnetism by hydrogen adsorption at the polar ZnO(0001) surface
The adsorption of hydrogen on the polar Zn-ended ZnO(0001) surface has been
investigated by density functional {\it ab-initio} calculations. An on top
H(1x1) ordered overlayer with genuine H-Zn chemical bonds is shown to be
energetically favorable. The H covered surface is metallic and spin-polarized,
with a noticeable magnetic moment at the surface region. Lower hydrogen
coverages lead to strengthening of the H-Zn bonds, corrugation of the surface
layer and to an insulating surface. Our results explain experimental
observations of hydrogen adsorption on this surface, and not only predict a
metal-insulator transition, but primarily provide a method to reversible switch
surface magnetism by varying the hydrogen density on the surface.Comment: 4 pages, 3 figure
Evolución diagenética en los sedimentos carbonatados marinos del Pleistoceno de Mallorca
Abstract not availabl
Pleuritis en la Valencia romana
X Congreso Nacional de PaleopatologĂa. Univesidad AutĂłnoma de Madrid, septiembre de 200
Magnetism and half-metallicity at the O surfaces of ceramic oxides
The occurence of spin-polarization at ZrO, AlO and MgO
surfaces is proved by means of \textit{ab-initio} calculations within the
density functional theory. Large spin moments, as high as 1.56 , develop
at O-ended polar terminations, transforming the non-magnetic insulator into a
half-metal. The magnetic moments mainly reside in the surface oxygen atoms and
their origin is related to the existence of holes of well-defined spin
polarization at the valence band of the ionic oxide. The direct relation
between magnetization and local loss of donor charge makes possible to extend
the magnetization mechanism beyond surface properties
Automatic system for the determination of metals by anodic stripping potentiometry in non-deaerated samples
An automatic system for the determination of Zn, Cd, Pb and Cu by anodic stripping potentiometry using the oxygen dissolved in the sample as oxidant is reported. The system relies on the use of a PC-compatible computer for instrumental control and data acquisition and processing
Enhanced electron correlations, local moments, and Curie temperature in strained MnAs nanocrystals embedded in GaAs
We have studied the electronic structure of hexagonal MnAs, as epitaxial
continuous film on GaAs(001) and as nanocrystals embedded in GaAs, by Mn 2p
core-level photoemission spectroscopy. Configuration-interaction analyses based
on a cluster model show that the ground state of the embedded MnAs nanocrystals
is dominated by a d5 configuration that maximizes the local Mn moment.
Nanoscaling and strain significantly alter the properties of MnAs. Internal
strain in the nanocrystals results in reduced p-d hybridization and enhanced
ionic character of the Mn-As bonding interactions. The spatial confinement and
reduced p-d hybridization in the nanocrystals lead to enhanced d-electron
localization, triggering d-d electron correlations and enhancing local Mn
moments. These changes in the electronic structure of MnAs have an advantageous
effect on the Curie temperature of the nanocrystals, which is measured to be
remarkably higher than that of bulk MnAs.Comment: 4 figures, 2 table
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